Napoli head to the Estadio de la Cerámica to face Villarreal on Wednesday 14 October (6:00am AEDT). Read on for our Villarreal vs Napoli prediction and the best Champions League odds at Ladbrokes.
We were keen on backing any team coming up against the struggling Villarreal, who have lost seven of their last eight Champions League matches.
That’s not a good sign for a club with a proud Champions League record. Napoli can take advantage of that lack of confidence, with two wins and a draw from their last five games.
Napoli at $3.10 are worth including in your Champions League Matchday 2 tips as a live underdog.
Villarreal vs Napoli Odds & Popular Betting Markets
Here’s a quick look at the current odds and popular betting markets for the Villarreal vs Napoli matchup.
*odds are correct at the time of publishing and are subject to change
| Team | Odds | |
|---|---|---|
| Villarreal CF/Villarreal CF | 3.20 | Bet Now |
| Draw/Villarreal CF | 5.50 | Bet Now |
| SSC Napoli/SSC Napoli | 4.60 | Bet Now |
| Draw/Draw | 6.00 | Bet Now |
| Draw/SSC Napoli | 7.50 | Bet Now |
| Villarreal CF/Draw | 11.00 | Bet Now |
| SSC Napoli/Draw | 11.00 | Bet Now |
| SSC Napoli/Villarreal CF | 17.00 | Bet Now |
| Villarreal CF/SSC Napoli | 21.00 | Bet Now |
UEFA Champions League odds correct as of 12/10/2026 and subject to change. Event scheduled to start at 14/10/2026 5:00am AEST.